Metallosupermolecular architectures and inorganic-organic polyoxometalete based hybrides

Project funded by Croatian Science Foundation (HRZZ) (Research Projects), grant IP-2016-06-4221. Participating organisations named by the source: Prirodoslovno-matematički fakultet, Zagreb; University of Zagreb, Faculty of Textile Technology. Funded amount: EUR 113,876, as stated by the source. Runs 2017-03-01 to 2021-02-28. Keywords: metallosupramolecular compounds, poyoxometalates, hybrides, hydrazones, dicarboxylate, structure. Source: OpenAIRE Graph, from the funder's project data (collected by OpenAIRE on 2026-07-23); national funding data, not CORDIS; selected because its keywords name quantum. Abstract given by the source: The main idea of the project is to apply principles of coordination chemistry to design and synthesise new MoVI metallosupramolecular architectures and POM-based organic-inorganic hybrid materials. Such systems will be developed via a bottom-up approach combining suitable building blocks generated in situ in solution as well as in the solid state. The complexity in their construction is an invaluable opportunity to study the self-assembly and crystal growth processes. Links between all segments of this research are in finding suitable conditions that are necessary to control the composition and/or structural features of target architectures. It is expected that our investigation will give insight into particular reaction mechanisms and provide explanation for the influence of different inter- and intramolecular interactions on properties of high-dimensional compounds or their building blocks. Methods used in the synthesis of organic, metallosupramolecular and inorganic-organic hybrids will be modified and performed in accordance to conventional, but also green, chemical methodologies. Investigations of thermally induced reactions in the solid state are additional challenging part of the project. The proposed project will combine organic, coordination, analytical, theoretical, biochemical and medicinal chemistry. The proposed project consists of the following parts: (i) design and synthesis of multifunctional hydrazone N,O-donor ligands and study of their properties; (ii) synthesis of novel MoVI metallosupramolecular architectures; (iii) preparation of novel hybrid organic-inorganic compounds based on polyoxomolybdates; (iv) characterisation of all prepared compounds; (v) quantum chemical calculations and theoretical support to the experimental research which will be used to understand and guide the improved efficiency of the studied processes; (vi) investigation of chemical and physical properties of prepared compounds; (vii) investigation of biological properties [shortened; the full text is on the OpenAIRE page]

Original source.

Source: OpenAIRE Graph: projects of national funders, OpenAIRE, from the project data of Croatian Science Foundation (HRZZ). Retrieved 2026-10-28. Licence: Creative Commons Attribution 4.0 (OpenAIRE Graph). Selected metadata, adapted presentation; the publisher's record is authoritative. No endorsement by the source is implied. Licence: Creative Commons Attribution 4.0 (CC BY 4.0).

AI-assisted summary: The project "Metallosupermolecular architectures and inorganic-organic polyoxometalete based hybrides" is funded by the Croatian Science Foundation with a grant of EUR 113,876, running from March 1, 2017, to February 28, 2021, involving the University of Zagreb. Suggested technology pillar: enabling. Generated by AI from the public source text; it may contain errors and the original source is authoritative.